6 edition of Hydrogen bonded polymers found in the catalog.
Includes bibliographical references and indexes.
|Statement||volume editor, Wolfgang Binder ; with contributions by W.H. Binder ... [et al.].|
|Series||Advances in polymer science -- v. 207|
|LC Classifications||QD381.9.S87 H95 2007|
|The Physical Object|
|Pagination||x, 206 p. :|
|Number of Pages||206|
|LC Control Number||2006938343|
Hydrogen bond or hydrogen bonding is a type of weak force that results in the formation of dipole-dipole interaction between a hydrogen atom and an electronegative atom that is strongly bonded to another electronegative atom. The bond or bonds are mostly strong in comparison to normal dipole-dipole and dispersion forces. A polymer is a large molecule a. made up of long chains of atoms held together by hydrogen bonds b. made up of long chains of atoms covalently bonded together c. made up of a large lattice structure held together by ionic bonds d. always made up of identical monomer units.
A polymer (/ ˈ p ɒ l ɪ m ər /; Greek poly-, "many" + -mer, "part") is a large molecule, or macromolecule, composed of many repeated subunits. Due to their broad range of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers . The paper contributes to the characterization and understanding the mutual interactions of the polar polymer gate dielectric and organic semiconductor in organic field effect transistors (OFETs). It has been shown on the example of cyanoethylated polyvinylalcohol (CEPVA), the high-k dielectric containing strong polar side groups, that the conditions during dielectric layer .
Figure Possible hydrogen-bonded structure for crystallites of ny an amide-type polymer of hexanedioic acid and 1,6-hexanediamine. The effect of temperature on the physical properties of polymers is very important to their practical uses. The right mix of hydrogen bonds in polymer and cement composites is critical to making strong, tough and ductile infrastructure material, according to researchers at Rice University who want to mimic the mechanics of mother-of-pearl and similar natural composites with synthetic materials.
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Hydrogen Bonded Polymers. Editors; Wolfgang Binder; Book. Citations; k Downloads; Part of the Advances in Polymer Science book series (POLYMER, volume ) Log in to check access. Buy eBook. USD Instant download; Readable on all devices; Own it forever; Local sales tax included if applicable.
Series: Advances in Polymer Science () (Book ) Hardcover: pages; Publisher: Springer; edition (Ma ) Language: English; ISBN ; ISBN ; Product Dimensions: x x inches Shipping Weight: 1 pounds (View shipping rates and policies) Customer Reviews: Be the first to write a reviewPrice: $ From the Back Cover S ummarizing our current knowledge of the topic, this book describes the roles and effects of hydrogen bonding in polymer materials by reviewing the latest developments over recent by: 2.
Summarizing our current knowledge of the topic, this book describes the roles and effects of hydrogen bonding in polymer materials by reviewing the latest developments over recent years.
To this end, it discusses all relevant aspects from the fundamentals, via characterization, to properties and applications in various polymeric. Supramolecular Polymers and Networkswith Hydrogen Bonds in the Main- and Side-Chain.
Pages Binder, Wolfgang H. (et al.)Brand: Springer-Verlag Berlin Heidelberg. The third part introduces the formation of hollow and giant macrocycles directed by hydrogen bonding, while the last part summarizes hydrogen bonded supramolecular polymers. This book is designed to bring together in a single volume the many important aspects of hydrogen bonding supramolecular chemistry and will be a valuable resource for graduates and researchers.
Hydrogen bonding can Hydrogen bonded polymers book significant effects on the physical properties of Hydrogen bonded polymers book, including their values of Tg or Tm, their dynamic behavior, and the crystallinity of structures. Based on the P Physical Properties of Hydrogen‐Bonded Polymers - Hydrogen Bonding in Polymeric Materials - Wiley Online Library Skip to Article Content.
Proton-accepting polymers can associate with proton-donating polymers via hydrogen bonding in aqueous solutions and form polymer-polymer or interpolymer complexes. There has been an increased interest among researchers in hydrogen-bonded interpolymer complexes since the first pioneering papers were published in the early s.
Part of the Advances in Polymer Science book series (POLYMER, volume ) Combining supramolecular principles with block copolymer self-assembly offers unique possibilitiesto create materials with responsive and/or tunable properties. The present chapter focuses on supramolecularmaterials based on hydrogen bonding and (block co-) by: Assignments of bands due to hydrogen-bonded groups are made on the basis of whether the proton and oxygen in a particular OH group are both involved in hydrogen bonds (as “donors” and “acceptors”, respectively) or whether one or the other is “free” (not hydrogen-bonded).
Hydrogen is an exception to the octet rule; its nearest noble gas, helium, has only two electrons. Hydrogen nuclei form molecules with two nearby electrons, a duet rule. To show a covalent bond, two chemical symbols are put near each other with two dots, representing a pair of electrons, between them.
For example, a water molecule has one oxygenFile Size: KB. The hydrogen bond is the research subject of many scientists from different branches of science. A general review and historical survey, dating back to the beginning of 20th century, has been published by Jeffrey as a monograph: An Introduction to Hydrogen Bonding .
The importance of the hydrogen bond is by: The present chapter focuses on supramolecular materials based on hydrogen bonding and (block co-) polymers. Several cases will be discussed where the self-assembled nanostructured morphology can be easily tuned using composition as the natural variable.
A large body of the material reviewed concerns hydrogen-bonded side-chain (block co-) by: In book: Hydrogen Bonding in Polymeric Materials, First, pp Cite this publication Hydrogen bonding in polymer blends is a topic of great interest to polymer Author: Shiao-Wei Kuo.
Here, we report a series of hydrogen-bonded supramolecular polymers P4VP (Z -TCS) x composed of poly (4-vinyl pyridine) (P4VP) as main chain and an α-cyanostilbene derivative (Z -TCS) as side groups.
The polymers show excellent photoinduced deformation ability under UV irradiation, in terms of both bending speed and bending angle. Supramolecular polymers and networks with hydrogen bonds in the main and side-chain / W.H.
Binder, R. Zirbs --Assembly via hydrogen bonds of low molar mass compounds into supramolecular polymers / L. Bouteiller --Supramolecular materials based on hydrogen-bonded polymers / G. ten Brinke, J. Ruokolainen, O. Ikkala --Nanocomposites based on.
The quantitative relationship between polymer structure and water solubility is probably more complex than a mere molar additive rule [6,7] but, no doubt, water solubility is closely related to the content of polar groups in the polymer and to the strength of the hydrogen bonds that they are able to establish with water molecules.
Not all polar Cited by: 5. Coil–helix transition by the intramolecular hydrogen bonding between neighboring monomers, hydration of a polymer chain in aqueous media, and competition in hydrogen bonding in the mixed solvents are detailed.
Conformation of polymers. Internal coordinates of a polymer chain and its hindered rotation. Novel visible-light responsive hydrogen-bonded supramolecular polymers have been successfully constructed by using a linear molecule, which consists of two ureido-pyrimidinone (UPy) moieties connected by a photochromic ortho -tetrafluorinated azobenzene (TFAB) linker.
Polymer Physics - by Fumihiko Tanaka April their functionality, and intermolecular associative forces (hydrogen bonding, hydrophobic force, electrostatic interaction, etc.). The goal of this book is thus to present polymer physics as generally as possible, striving to maintain the appropriate balance between theoretical.
packing–27 It is crucial to manipulate both the intermolecular interactions (non- covalent bonds) and the macromolecular characteristics (rigid ladder-type back-bone) to precisely control the properties and functions of ladder polymers In the context of this challenge, hydrogen bonds have been recognized as an ideal.This paper reports on synthesis, acid–base properties, and self-structuring in water of a chiral polyamidoamino acid, M-l-Gln, obtained from the polyaddition of N,N′-methylenebisacrylamide with l-glutamine, with the potential of establishing hydrogen bonds through its prim-amide pendants.
The M-l-Gln showed pH-responsive circular dichroism spectra, revealing ordered. Units of 2-ureidopyrimidone that dimerize strongly in a self-complementary array of four cooperative hydrogen bonds were used as the associating end group in reversible self-assembling polymer systems.
The unidirectional design of the binding sites prevents uncontrolled multidirectional association or gelation. Linear polymers and reversible networks Cited by: